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Refractory multi-principal element alloys (RMPEAs), HfNbTaTiZr, (HfNbTaTiZr)9Cr and (HfNbTaTiZr)9Al, were manufactured using vacuum arc melting followed by laser-remelting to mimic additive manufacturing. The microhardness of as-cast HfNbTaTiZr, (HfNbTaTiZr)9Cr and (HfNbTaTiZr)9Al samples after arc melting was measured as 6.20, 7.63 and 6.89 GPa, respectively. After laser-remelting and re-solidification, the hardness increased by ~30% for each composition; the hardest was (HfNbTaTiZr)9Cr measured at 9.60 GPa, and the softest was HfNbTaTiZr with a hardness of 8.42 GPa, which was still harder compared to all the as-cast samples. The addition of Al and Cr led to enhanced oxidation resistance for the respective RMPEA systems. The Al-containing composition showed the best oxidation resistance for the as-cast samples; however, after laser remelting, the Cr-containing RMPEA had the best overall oxidation resistance, and the increase in weight after oxidation dropped by 42% when compared to that for the as-cast alloy. Laser remelting the RMPEAs led to an improvement in mechanical properties; it also resulted in enhanced oxidation resistance for (HfNbTaTiZr)9Cr. However, laser remelting barely changed the oxidation resistance for (HfNbTaTiZr)9Al, and it decreased the oxidation resistance for HfNbTaTiZr. These phenomena are related to microstructure changes induced by the laser remelting/additive manufacturing as compared to conventional casting-based manufacturing.more » « less
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Rittenhouse, Joshua; Luebbe, Matthew; Hoffman, Andrew; Liu, Yuzi; Rebak, Raul B; Islamgaliev, Rinat K; Valiev, Ruslan Z; Jalan, Visharad; Wen, Haiming (, Corrosion Science)FeCrAl alloys are promising candidates to replace Zr alloys as fuel cladding materials in nuclear light-water reactors. Grain refinement has been indicated to improve irradiation resistance. To enhance corrosion resistance as well, the effects of grain refinement on steam corrosion behavior were investigated in this work. Samples of Kanthal D alloy (Fe-21Cr-5Al) with two different grain sizes (coarse-grained and ultrafine-grained) were exposed to steam at 1200 °C for 2 hrs. Results indicate improved steam corrosion resistance in ultrafine-grained Kanthal D with formation of a thinner protective Al oxide layer and the presence of a thin underlying Cr oxide layer.more » « less
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